# 1 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp"
;jc-hsqcetgp
;avance-version (09/04/17)
;HSQC
;2D H-1/X correlation via double inept transfer
;phase sensitive using Echo/Antiecho-TPPI gradient selection
;with decoupling during acquisition
;with heteronuclear J-compensation in the range of 120-250 Hz (for d5=1)
;
;$CLASS=HighRes
;$DIM=2D
;$TYPE=
;$SUBTYPE=
;$COMMENT=


# 1 "/opt/topspin3.0/exp/stan/nmr/lists/pp/Avance.incl" 1
;Avance3.incl
;   for AV III
;
;avance-version (07/12/14)
;
;$CLASS=HighRes Incl
;$COMMENT=
# 165 "/opt/topspin3.0/exp/stan/nmr/lists/pp/Avance.incl"
;$Id: Avance3.incl,v 1.9 2009/07/02 16:40:43 ber Exp $
# 16 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp" 2

# 1 "/opt/topspin3.0/exp/stan/nmr/lists/pp/Grad.incl" 1
;Grad2.incl  -  include file for Gradient Spectroscopy
;   for 1
;
;avance-version (07/01/17)
;
;$CLASS=HighRes Incl
;$COMMENT=

# 27 "/opt/topspin3.0/exp/stan/nmr/lists/pp/Grad.incl"
define list<gradient> EA=<EA>


# 31 "/opt/topspin3.0/exp/stan/nmr/lists/pp/Grad.incl"
;$Id: Grad2.incl,v 1.13 2009/07/02 16:40:43 ber Exp $
# 17 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp" 2

# 1 "/opt/topspin3.0/exp/stan/nmr/lists/pp/Delay.incl" 1
;Delay.incl  -  include file for commonly used delays
;
;version 00/02/07
;
;$CLASS=HighRes Incl
;$COMMENT=

# 9 "/opt/topspin3.0/exp/stan/nmr/lists/pp/Delay.incl"
;general delays

define delay DELTA
define delay DELTA1
define delay DELTA2
define delay DELTA3
define delay DELTA4
define delay DELTA5
define delay DELTA6
define delay DELTA7
define delay DELTA8

define delay TAU
define delay TAU1
define delay TAU2
define delay TAU3
define delay TAU4
define delay TAU5
# 29 "/opt/topspin3.0/exp/stan/nmr/lists/pp/Delay.incl"
;delays for centering pulses

define delay CEN_HN1
define delay CEN_HN2
define delay CEN_HN3
define delay CEN_HC1
define delay CEN_HC2
define delay CEN_HC3
define delay CEN_HC4
define delay CEN_HP1
define delay CEN_HP2
define delay CEN_CN1
define delay CEN_CN2
define delay CEN_CN3
define delay CEN_CN4
define delay CEN_CP1
define delay CEN_CP2

# 48 "/opt/topspin3.0/exp/stan/nmr/lists/pp/Delay.incl"
;loop counters

define loopcounter COUNTER
define loopcounter SCALEF
define loopcounter FACTOR1
define loopcounter FACTOR2
define loopcounter FACTOR3

# 58 "/opt/topspin3.0/exp/stan/nmr/lists/pp/Delay.incl"
;$Id: Delay.incl,v 1.13 2009/07/02 16:40:43 ber Exp $
# 18 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp" 2


# 21 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp"
"p2=p1*2"
"p4=p3*2"
"d11=30m"
"acqt0=0"

"d20=d5*0.001469"
"d21=d5*0.00213465"
"d22=d5*0.0003938"
"DELTA1=d5*0.001469-p16-4u"
"DELTA3=p16+d16-4u"

"DELTA=p16+d16+p26+d0*2"
# 34 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp"
"d0=3u"
"in0=inf1/2"

# 1 "mc_line 37 file /opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp exp. def. part of mc cmd. before ze"
define delay MCWRK
define delay MCREST
define delay d0orig
"d0orig=d0"
define loopcounter t1loop
"t1loop=0"
define loopcounter ph1loop
"ph1loop=0"
define loopcounter ST1CNT
"ST1CNT = td1/(2)"
"MCWRK = 0.090909*d1"
"MCREST = d1 - d1"

    dccorr
# 37 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp"
1 ze
# 1 "mc_line 37 file /opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp exp. def. of mc cmd. after ze"
# 38 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp"
  d11 pl12:f2
# 1 "mc_line 39 file /opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp exp. start label for mc cmd."
2 MCWRK  * 5 do:f2
LBLF1, MCWRK  * 5
LBLST1, MCWRK 
  MCREST
# 40 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp"
3 (p21:sp21 ph1):f1		;zx
  
  d20 pl2:f2
  (p22:sp22 ph1):f1	(p22:sp23 ph1):f2	;URx180 BIBOP
  d20 setnmr3|0 setnmr0|34|32|33 ctrlgrad 0
   
  (p30:sp30 ph1):f1		;URx242  ;p1*2.7 ph1
  d21
  (p22:sp22 ph1):f1	(p22:sp23 ph1):f2	;URx180 BIBOP
  d21

  (p30:sp31 ph1):f1		;URx65  ;p1*0.72 ph1
  d22
  (p22:sp22 ph1):f1	(p22:sp23 ph1):f2	;URx180 BIBOP
  d22
  (p21:sp24 ph1):f1	(p21:sp25 ph3):f2	;yz z-y
      
  d0 
  (p26:sp26 ph5):f1
  d0
# 61 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp"
  p16:gp1*EA
  d16
  (p27:sp27 ph4):f2
  DELTA

  (p21:sp28 ph1):f1	(p21:sp29 ph4):f2	;z-y yz
  d22
  (p22:sp22 ph1):f1	(p22:sp23 ph1):f2	;URx180 BIBOP
  d22
  (p30:sp31 ph1):f1		;URx65  ;p1*0.72 ph1

  d21
  (p22:sp22 ph1):f1	(p22:sp23 ph1):f2	;URx180 BIBOP
  d21
  (p30:sp30 ph1):f1		;URx242  ;p1*2.7 ph1
   
  d20
  (p22:sp22 ph1):f1	(p22:sp23 ph1):f2	;URx180 BIBOP
  ;d20  
  p16:gp2
  DELTA1 setnmr3^0 setnmr0^34^32^33 ctrlgrad 7
  4u pl12:f2
# 85 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp"
  ;p16:gp2
  ;d16 setnmr3^0 setnmr0^34^32^33 ctrlgrad 7
  ;(p22:sp22 ph1):f1
  ;DELTA3
  ;4u pl12:f2
  
  go=2 ph31 ;cpd2:f2
# 1 "mc_line 92 file /opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp exp. mc cmd. in line"
  MCWRK  do:f2 wr #0 if #0 zd 

  "ph1loop+=1"
      "d0=d0orig + t1loop * in0 "
      "phval3 = (t1loop * 180)%360"
      MCWRK ip3 + phval3
      "phval6 = (t1loop * 180)%360"
      MCWRK ip6 + phval6
      "phval31 = (t1loop * 180)%360"
      MCWRK ip31 + phval31
      "phval0 = ph1loop * 1"
      MCWRK setgrad EA
  lo to LBLF1 times 2
  MCWRK 

  "t1loop+=1"
      "d0=d0orig + t1loop * in0 "
      "phval3 = (t1loop * 180)%360"
      MCWRK ip3 + phval3
      "phval6 = (t1loop * 180)%360"
      MCWRK ip6 + phval6
      "phval31 = (t1loop * 180)%360"
      MCWRK ip31 + phval31
      "phval0 = ph1loop * 1"
      MCWRK setgrad EA
  lo to LBLST1 times ST1CNT
  MCWRK 
  "t1loop=0"
  "ph1loop=0"
  MCWRK
# 94 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp"
exit
   

ph1=0 
ph2=1
ph3=0 2
ph4=0 0 2 2
ph5=0 0 0 0 2 2 2 2
ph6=0
ph31=0 2 2 0
  

;pl1 : f1 channel - power level for pulse (default)
;pl2 : f2 channel - power level for pulse (default)
;pl3 : f3 channel - power level for pulse (default)
;pl12: f2 channel - power level for CPD/BB decoupling
;p1 : f1 channel -  90 degree high power pulse
;p2 : f1 channel - 180 degree high power pulse
;p3 : f2 channel -  90 degree high power pulse
;p4 : f2 channel - 180 degree high power pulse
;p16: homospoil/gradient pulse
# 116 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp"
;p21 : 550u excitation pulses
;p22 : 600u UR and Inversion pulses
;p26 : 100u Inversion pulse
;p27 : 1100u UR pulse
;p30 : 200u odd UR pulses

;spnam21 : jc01_BEBOP_zx..
;spnam22 : jc02_BURBOP_x..
;spnam24 : jc04_BEBOP_yz..
;spnam26 : jc06_BIBOP_z-z..
;spnam28 : jc08_BEBOP_z-y..
;spnam30 : jc10_BURBOP_x242.8833deg..
;spnam31 : jc11_BURBOP_x65.3166deg..

;spnam23 : jc03_BIBOP..
;spnam25 : jc05_BEBOP_zy..
;spnam27 : jc07_BURBOP_y..
;spnam29 : jc09_BEBOP_-yz..
# 135 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp"
;sp21 : 20 kHz Rf Amplitude
;sp22 : 20 kHz Rf Amplitude
;sp24 : 20 kHz Rf Amplitude
;sp26 : 20 kHz Rf Amplitude
;sp28 : 20 kHz Rf Amplitude
;sp30 : 20 kHz Rf Amplitude
;sp31 : 20 kHz Rf Amplitude

;sp23 : 10 kHz Rf Amplitude
;sp25 : 10 kHz Rf Amplitude
;sp27 : 10 kHz Rf Amplitude
;sp29 : 10 kHz Rf Amplitude

# 149 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp"
;d0 : incremented delay (2D)                  [3 usec]
;d1 : relaxation delay; 1-5 * T1
;d4 : 1/(4J)XH
;d11: delay for disk I/O                             [30 msec]
;d16: delay for homospoil/gradient recovery
;d5: = 1 (for J=120-250Hz, Delay Scaling Factor)
;inf1: 1/SW(X) = 2 * DW(X)
;in0: 1/(2 * SW(X)) = DW(X)
;nd0: 2
;NS: 2 * n
;DS: >= 16
;td1: number of experiments
;FnMODE: echo-antiecho
;cpd2: decoupling according to sequence defined by cpdprg2
;pcpd2: f2 channel - 90 degree pulse for decoupling sequence


;use gradient ratio:	gp 1 : gp 2
;			  80 : 20.1    for C-13
;			  80 :  8.1    for N-15
# 170 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp"
;for z-only gradients:
;gpz1: 80%
;gpz2: 20.1% for C-13, 8.1% for N-15

;use gradient files:   
;gpnam1: SMSQ10.100
;gpnam2: SMSQ10.100

# 179 "/opt/topspin3.0/exp/stan/nmr/lists/pp/user/jc_hsqcetgp"
                                          ;preprocessor-flags-start

;$Id: hsqcetgp,v 1.5.2.1 2011/02/24 17:27:48 ber Exp $
